
Various lightweight metals such as Li, Na, Mg, etc. are the basis of promising rechargeable batteries, but aluminium has some unique advantages: (i) the most abundant metal in the Earth's crust, (ii) trivalent charge carrier storing three times more charge with each ion transfer in comparison with Li, (iii) the volumetric capacity of the Al anode is four times higher than that of Li while their gravimetric capacities are comparable, (iv) employing a metallic Al anode does not have a major safety risk as is the case for alkali metals. [pdf]
4. In this work aluminum was considered as energy storage and carrier. To produce 1 kg of aluminum, 2 kg of alumina, 0.4–0.5 kg of coal, 0.02–0.08 kg of cryolite and 13.4–20 kWh of electrical energy are required. Total energy intensity of aluminum was estimated to be about 100 MJ/kg.
Aluminum-based energy storage can participate as a buffer practically in any electricity generating technology. Today, aluminum electrolyzers are powered mainly by large conventional units such as coal-fired (about 40%), hydro (about 50%) and nuclear (about 5%) power plants , , , .
Calorific value of aluminum is about 31 MJ/kg. Only this energy can be usefully utilized within aluminum-fueled power plant. So, it shows the efficiency limit. If 112.8 MJ are deposited, the maximum cycle efficiency of aluminum-based energy storage is as follows: 31 MJ 72.8 MJ = 43 %. This percentage represents the total-thermal efficiency.
Energy storage capacity of aluminium Aluminium has a high storage density. Theoretically, 8.7 kWh of heat and electricity can be produced from 1 kg of Al, which is in the range of heating oil, and on a volumetric base (23.5 MWh/m 3) even surpasses the energy density of heating oil by a factor of two. 4.2. The Power-to-Al process
The coming of aluminum-based energy storage technologies is expected in some portable applications and small-power eco-cars. Since energy generation based on aluminum is cleaner than that of fossil fuel, the use of aluminum is defensible within polluted areas, e.g. within megapolises.
To produce 1 kg of aluminum, 2 kg of alumina, 0.4–0.5 kg of coal, 0.02–0.08 kg of cryolite and 13.4–20 kWh of electrical energy are required. Total energy intensity of aluminum was estimated to be about 100 MJ/kg. Cycle efficiency of aluminum-based energy storage does not exceed 43%. 5.
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