The purpose of this study is to elucidate the primary factors affecting the CH 4 hydrate self-preservation effect and to identify an optimal condition for the industrial application
Gas hydrates are promising components for a wide range of industries and the national economy. This paper outlines the gas hydrate application areas with the greatest potential. Gas hydrates of methane,
The validation of the model is done via comparison with experiments performed in a laboratory-scale pilot plant unit. Finally, a two-equation model is presented that can predict
The self-preservation effect of CH 4 hydrate can facilitate the solidified storage and transport of natural gas at mild temperature and pressure conditions. However, the factors
4 天之前· The utilization of NG for energy requires proper storage, transportation and distribution as with improper storage NG may leak from oil & gas facilities into the atmosphere, causing a
The ability of methane hydrates to exist outside of its standard stability zone is vital in many aspects, such as its utility in gas storage and transportation, hydrate-related climate changes...
Molecular simulation studies aforementioned provide the microscopic insights on the decomposition of gas hydrate, however, the self-preservation effect is clearly of distinct origins as it in fact prevents hydrates from decomposing above their melting point.
Continuous efforts have been made to strengthen the self-preservation effect for longer storage time and transport distance. For examples, Zhang and Rogers (2008) achieved ultra-stability of gas hydrates by using surfactant solutions to form gas hydrates with the help of aluminium tube, copper tube, or solid copper.
Gas hydrates could show an unexpected high stability at conditions out of thermodynamic equilibrium, which is called the self-preservation effect. The mechanism of the effect for methane hydrates is here investigated via molecular dynamics simulations, in which an NVT/E method is introduced to represent different levels of heat transfer resistance.
In this review, we have evaluated the status of gas storage via clathrate hydrate technology with a major focus on CH 4 and H 2 hydrates. Recent advances to moderate the hydrate equilibrium conditions and enhance hydrate formation kinetics are summarized.
Strategies to improve hydrate equilibrium, formation kinetics and storage stability. Development of greener, safer and more efficient promoters like amino acids. Shift of self-preservation effect to temperatures above 273.2 K for hydrate storage. Roadmap for a sustainable, efficient and economical hydrate technology for gas storage.
Experimental study shows that natural gas hydrates can be saved more than 1 year at temperature between 255 and 272 K 24. It is worthy to study how temperature and pressure affect the self-preservation effect on molecular level.
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