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Dalian Institute of Chemical Physics, Chinese Academy of Sciences - Cited by 49,277 - Graphene & 2D Materials - Energy Chemistry - Electrochemistry - Microscale Energy Storage - Batteries
关键词: γ-MnO 2, Graphene, Zinc-ion battery, High-capacity cathode Abstract: Aqueous Zn//MnO 2 batteries are emerging as promising large-scale energy storage devices owing to their cost
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A 10 kWh ZNB energy storage system was built and tested to further demonstrate the potential of ZNB in the application of energy storage devices in a larger scale. The system consists of ZNB stack with 300 batteries, BMS, power conversion system (PCS), power strip connected to the grid and a radiator.
ZNB has been successfully integrated with energy storage systems. The cost account of ZNB is calculated to compare with lead-acid battery. This work developed intrinsically safe zinc–nickel batteries (ZNB) with different capacities of 20 Ah and 75 Ah, respectively, for future fundamental studies and applications.
The coulombic efficiency is approximate to 100% before 200 cycles. The discharge capacity of ZNB is 13.8 Ah before the start of the decline of the coulombic efficiency at 711 h (200 cycles), illustrating the zinc-nickel battery can stably work for a long time under an extreme charge and discharge condition.
When the gasoline range–extender is turned on, the voltage of the ZNB stack can be rapidly increased to 72 V–74 V, and the current generated by the gasoline range–extender can assist the battery to reach the peak power of the electric motor of approximately 1300 W.
The application of the ZNB stacks as a power supply of an electric bicycle and a hybrid electric vehicle (HEV) is demonstrated. In addition, a solar power system and a 10 kWh ZNB energy storage system is built and tested to indicate the potential of ZNB in the application of energy storage devices.
The cycling performance of ZNB was tested according to the following procedure: the batteries were charged at a constant current of 1C until the potential reached 1.88 V (15.04 V for 12 V ZNB stack), and kept charging at a constant voltage of 1.88 V to a cutoff current of 0.5 A.
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