
In particular, inorganic anode materials such as Sn, metallic selenides, and hybrid materials have gained recognition as promising candidates for SIBs. 6 Among the carbonaceous materials, hard carbons are considered one of the most promising solutions for anode materials in SIBs due, among others, to their turbostratic structure, providing a high volume of closed porosity. 7 The exploitation of hard carbons as anode materials in SIBs has shown promising electrochemical energy storage performance, reaching specific capacity values of more than 300 mA h g −1 with a long plateau close to sodium's reduction potential. [pdf]
For SIB anode materials, hard carbon is the most mature and currently the only material likely to be commercialized, but it is still far away from large-scale industrialization. Herein, we carry out a comprehensive overview of the current state of the art in terms of three main aspects.
Hard carbon (HC) is recognized as a promising anode material with outstanding electrochemical performance for alkali metal-ion batteries including lithium-ion batteries (LIBs), as well as their analogs sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs).
In recent years, coal-based hard carbon has received widespread attention as an anode material for sodium-ion batteries [19, 20]. To date, coal-based hard carbon is a promising anode material for sodium-ion batteries due to its high storage capacity, appropriately low operating potential and relatively stable source.
Hard carbon still suffers from unclear sodium storage mechanism, unsatisfactory performance, and low initial Coulombic efficiency (ICE). Herein, the current state-of-the-art advances in designing hard carbon anodes for high-performance SIBs is summarized.
Hard carbon (HC) is a promising anode candidate for Na-ion batteries (NIBs) because of its excellent Na-storage performance, abundance, and low cost. However, a precise understanding of its Na-storage behavior remains elusive.
This indicates the existence of three types of sodium ion storage sites in the hard carbon anode.
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